Polyethylene glycol grafted with carboxylated graphene oxide as a novel interface modifier for polylactic acid/graphene nanocomposites

Autor: Mingjun Niu, Hao Wang, Jing Li, Hongyan Chen, Lin Li, Huige Yang, Xuying Liu, Zhihao Chen, Hongzhi Liu, Jinzhou Chen
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Royal Society Open Science, Vol 7, Iss 7 (2020)
Druh dokumentu: article
ISSN: 2054-5703
84261382
DOI: 10.1098/rsos.192154
Popis: Strength and toughness are both of great importance for the application of polylactic acid (PLA). Unfortunately, these two properties are often contradictory. In this work, an effective and practical strategy is proposed by using carboxylated graphene oxide (GC) grafted with polyethylene glycol (PEG), i.e. GC-g-PEG. The synthesis procedure of GC-g-PEG is firstly optimized. Then, a series of PLA nanocomposites were prepared by the melt blending method via masterbatch. In comparison to that achieved over pure PLA, these nanocomposites are of higher crystallinity, thermal stability and mechanical strength. This is mainly attributed to well-tailored interface and good dispersion. Especially, while retaining the tensile strength of the original PLA, the elongation at break increases by seven times by adding 0.3 wt% GC-g-PEG.
Databáze: Directory of Open Access Journals