cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylate

Autor: Naeema Khan, Andreas Fischer, Sadaf Saeed, Mashooda Hasan, Samina Alam
Jazyk: angličtina
Rok vydání: 2008
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 64, Iss 2, Pp o361-o361 (2008)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536807066020
Popis: The title compound, C16H20N2O2, was synthesized from (S)-tryptophan methyl ester hydrochloride and butyraldehyde. The absolute configuration 9S,10S was assigned on the basis of the unchanging chirality of the C9 centre. The NH group of the indole ring is involved in intermolecular N—H...O hydrogen bonding, while the NH group of the six-membered ring is not. This latter ring has a half-chair conformation.
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