2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate

Autor: Reginald B. H. Tan, Pui Shan Chow, Srinivasulu Aitipamula, Guangwen He
Jazyk: angličtina
Rok vydání: 2010
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 66, Iss 12, Pp o3339-o3340 (2010)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536810049093
Popis: In the title salt, C5H7N2+·C10H9O2−, 2-aminopyridine and 1-phenylcyclopropane-1-carboxylic acid crystallize together, forming a 2-aminopyridinium–carboxylate supramolecular heterosynthon involving two N—H...O hydrogen bonds, which in turn dimerizes to form a four-component supramolecular unit also sustained by N—H...O hydrogen bonding. A C—H...π interaction between a pyridine C—H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supramolecular unit. The overall crystal packing also features C—H...O interactions.
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