mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN1]bis(2-quinolylphenyl-κ2C1,N)iridium(III) deuterochloroform disolvate
| Autor: | Peter G. Jones, Andreas Freund, Marc Debeaux, Wolfgang Kowalsky, Hans-Hermann Johannes |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 11, Pp m1408-m1409 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810038596 |
| Popis: | In the title compound, [Ir(C13H9N4)(C15H10N)2]·2CDCl3, the coordination at iridium is octahedral, but with narrow ligand bite angles ranging from 74.85 (8) to 83.99 (8)°. The bond lengths at iridium show the expected trans influence, with Ir—N trans to C being appreciably longer than trans to N. The chelate rings are mutually perpendicular to a reasonable approximation [interplanar angles ranging from 77.79 (6) to 83.93 (7)°]. All ligands are approximately planar; the maximum interplanar angles within ligands are ca 12°. One CDCl3 solvent molecule is severly disordered and was excluded from the refinement. |
| Databáze: | Directory of Open Access Journals |
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