4-Cyano-1-(4-nitrobenzyl)pyridinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato-κ2S4,S5)nickelate(III)
| Autor: | Chong-Zhen Mei, Qing-Duo Lei, Kai-Hui Li |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 10, Pp m1311-m1311 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810037426 |
| Popis: | In the title salt, (C13H10N3O2)[Ni(C3S5)2], the NiIII cation is S,S′-chelated by two 2-thioxo-1,3-dithiole-4,5-dithiolate anions in a distorted square-planar geometry. The complex anion is approximately planar with a maximum deviation of 0.097 (1) Å. In the 1-(4-nitrobenzyl)-4-cyanopyridinium cation, the pyridine ring is twisted at a dihedral angle of 73.84 (16)° with respect to the benzene ring. π-π stacking is observed between nearly parallel [dihedral angle = 4.71 (7)°] dithiole and benzene rings, the centroid–centroid distance being 3.791 (2) Å. |
| Databáze: | Directory of Open Access Journals |
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