N-(2-Bromobenzyl)cinchoninium bromide

Autor: Agnieszka Skórska-Stania, Magdalena Jezierska-Zięba, Barbara Kąkol, Michał Fedoryński, Barbara J. Oleksyn
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 68, Iss 9, Pp o2803-o2804 (2012)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S160053681203646X
Popis: The title compound {systematic name: 1-(2-bromobenzyl)-5-ethenyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azabicyclo[2.2.2]octan-1-ium bromide}, C26H28BrN2O+·Br−, is a chiral quaternary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromobenzyl substituent are inclined to one another by 9.11 (9)°. A weak intramolecular C—H...O hydrogen bond occurs. The crystal structure features strong O—H...Br hydrogen bonds and weak C—H...Br interactions.
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