Hetero-Bimetallic Ferrocene-Containing Zinc(II)-Terpyridyl-Based Metallomesogen: Structural and Electrochemical Characterization
| Autor: | Evelyn Popa, Adelina A. Andelescu, Sorina Ilies (b. Motoc), Alexandru Visan, Carmen Cretu, Francesca Scarpelli, Alessandra Crispini, Florica Manea, Elisabeta I. Szerb |
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| Jazyk: | angličtina |
| Rok vydání: | 2023 |
| Předmět: |
Zn(II)/ferrocene metallomesogen
hetero-bimetallic coordination complex PXRD studies cyclic voltammetry electrochemistry Technology Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 |
| Zdroj: | Materials, Vol 16, Iss 5, p 1946 (2023) |
| Druh dokumentu: | article |
| ISSN: | 1996-1944 |
| DOI: | 10.3390/ma16051946 |
| Popis: | The synthesis, as well as the mesomorphic and electrochemical properties, of a hetero-bimetallic coordination complex able to self-assemble into a columnar liquid crystalline phase is reported herein. The mesomorphic properties were investigated by polarized optical microscopy (POM), differential scanning calorimetry (DSC) and Powder X-ray diffraction (PXRD) analysis. Electrochemical properties were explored by cyclic voltammetry (CV), relating the hetero-bimetallic complex behaviour to previously reported analogous monometallic Zn(II) compounds. The obtained results highlight how the presence of the second metal centre and the supramolecular arrangement in the condensed state pilot the function and properties of the new hetero-bimetallic Zn/Fe coordination complex. |
| Databáze: | Directory of Open Access Journals |
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