catena-Poly[[trans-bis(1,3-benzothiazole-κN)manganese(II)]-di-μ-chlorido]
| Autor: | Hasna Bouchareb, Sabrina Benmebarek, Sofiane Bouacida, Hocine Merazig, Mhamed Boudraa |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 7, Pp m275-m275 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 |
| DOI: | 10.1107/S1600536814014159 |
| Popis: | In the title coordination polymer, [MnCl2(C7H5NS)2]n, the MnII ion is located on the intersection of a twofold rotation axis and a mirror plane and adopts an octahedral coordination geometry defined by two mutually trans N atoms from benzothiazole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The MnII ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring π–π stacking interactions with a centroid–centroid distance of 3.6029 (15) Å. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|