The Intramolecular Radical Cation Induced Diels-Alder Reaction in the Diene - Diene Format

Autor: Paul G. Gassman, David B. Gorman, David B. Rusterholz
Jazyk: angličtina
Rok vydání: 1997
Předmět:
Zdroj: Molecules, Vol 2, Iss 5, Pp 80-86 (1997)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/20500080
Popis: Two 1,3,8,10-undecatetraenes were synthesized to test the viability of the intramolecular radical cation induced Diels-Alder reaction in the diene - diene format. Cyclization was successful only for the substituted tetraene with the lower oxidation potential. The major hexahydroindene product possessed a trans ring juncture demonstrating a selectivity for the endo stereochemistry.
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