SYNTHESIS OF TRIPHENYLAMINE-BASED RHOMBIMINE MACROCYCLE BY [2+2] CYCLOCONDENSATION REACTION BETWEEN (1R,2R)-DIAMINOCYCLOHEXANE AND 4,4’-DIFORMYL TRIPHENYLAMINE
Autor: | Loredana Vacareanu (Stafie), Virgil Barboiu, Daniel Timpu, Mircea Grigoras |
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Jazyk: | angličtina |
Rok vydání: | 2009 |
Předmět: | |
Zdroj: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 4, Iss 1, Pp 97-102 (2009) |
Druh dokumentu: | article |
ISSN: | 1857-1727 2345-1688 |
Popis: | A Schiff base macrocycle with persistent rhomboidal shape was synthesized in excellent yield through [2+2] condensation reaction between (R,R)-1,2-diaminocyclohexane and 4,4’-diformyltriphenylamine. The dimeric macrocylic structure was proved by electrospray ionization mass spectrometry (ESI-MS), 1H-NMR, and FTIR spectroscopy. The complexation properties were evidenced by UV absorption. |
Databáze: | Directory of Open Access Journals |
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