| Autor: |
Xu‐Feng Luo, Jagabandhu Patra, Wei‐Tsung Chuang, Thi Xuyen Nguyen, Jyh‐Ming Ting, Ju Li, Chih‐Wen Pao, Jeng‐Kuei Chang |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Advanced Science, Vol 9, Iss 21, Pp n/a-n/a (2022) |
| Druh dokumentu: |
article |
| ISSN: |
2198-3844 |
| DOI: |
10.1002/advs.202201219 |
| Popis: |
Abstract Transition metal high‐entropy oxides (HEOs) are an attractive class of anode materials for high‐performance lithium‐ion batteries (LIBs). However, owing to the multiple electroactive centers of HEOs, the Li+ storage mechanism is complex and debated in the literature. In this work, operando quick‐scanning X‐ray absorption spectroscopy (XAS) is used to study the lithiation/delithiation mechanism of the Cobalt‐free spinel (CrMnFeNiCu)3O4 HEO. A monochromator oscillation frequency of 2 Hz is used and 240 spectra are integrated to achieve a 2 min time resolution. High‐photon‐flux synchrotron radiation is employed to increase the XAS sensitivity. The results indicate that the Cu2+ and Ni2+ cations are reduced to their metallic states during lithiation but their oxidation reactions are less favorable compared to the other elements upon delithiation. The Mn2+/3+ and Fe2+/3+ cations undergo two‐step conversion reactions to form metallic phases, with MnO and FeO as the intermediate species, respectively. During delithiation, the oxidation of Mn occurs prior to that of Fe. The Cr3+ cations are reduced to CrO and then Cr0 during lithiation. A relatively large overpotential is required to activate the Cr reoxidation reaction. The Cr3+ cations are found after delithiation. These results can guide the material design of HEOs for improving LIB performance. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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