A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)

Autor: Wen-Dong Song, Peng-Zhi Hong, Run-Zhen Fan
Jazyk: angličtina
Rok vydání: 2008
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 64, Iss 2, Pp m289-m289 (2008)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536807067815
Popis: The title complex, [Co(C8H12N2O3)2(C3H4N2)2], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally coordinated by two N atoms from two barbital ligands and two N atoms from two imidazole ligands. The molecules are self-assembled via intermolecular N—H...O hydrogen-bonding interactions into a supramolecular network.
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