Multi peak emission and morphological evolution of Fe-doped ZnOs nanoflowers

Autor: Neelamkodan Hind, Megha Unikoth, Binitha Puzhakkara Manathanath
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Processing and Application of Ceramics, Vol 17, Iss 2, Pp 149-156 (2023)
Druh dokumentu: article
ISSN: 1820-6131
2406-1034
DOI: 10.2298/PAC2302149N
Popis: The nanoflowers and nanoblocks of Fe-doped ZnO (i.e. ZnO doped with 0, 1, 2, 3, 4 and 5% Fe) were synthesised by co-precipitation technique. XRD analysis showed that the samples have wurtzite structure containing mostly Fe3+ in the samples with 1% Fe and a mixture of Fe3+ and Fe2+ in the samples with higher amount of dopant. Morphology transformations from nanoflowers to nanoblocks, then into a combination of nanoflowers and nanoblocks were observed. The UV analysis identified the presence of multi-absorption regions in the doped samples. Due to the elevated Fe2+ concentration, the band gap of the 5% doped nanoblocks expanded and behaved irregularly. The room temperature photoluminescence characteristics of the Fe-doped ZnO nanostructures were determined. It was found that, in addition to the detected peaks in the yellow and red regions, the sample doped with 1%Fe shows two peaks in the blue region which could be interesting for multifunctional applications in the field of optoelectronics.
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