Autor: |
Yeon-Joo Cheong, Mi-hyun Lee, Heemin Byeon, Jiyong Park, Sungju Yu, Hye-Young Jang |
Jazyk: |
angličtina |
Rok vydání: |
2022 |
Předmět: |
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Zdroj: |
Catalysts, Vol 12, Iss 6, p 656 (2022) |
Druh dokumentu: |
article |
ISSN: |
2073-4344 |
DOI: |
10.3390/catal12060656 |
Popis: |
The iridium(Ir) (triNHC = tri-N-heterocyclic carbene)-catalyzed transfer hydrogenation of glycerol carbonate (GC) is described in the absence of additional hydride sources. The described reduction provides a sustainable route to produce industrially-valuable formate and lactate with high turnover numbers (TONs). The bimetallic Ir(I) involving triNHC carbene ligands exhibits high TONs, and the reaction mechanism, including the bimetallic Ir(triNHC) catalyst, is proposed based on mechanistic studies. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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