Tetrapotassium heptacyanidomolybdate(III) dihydrate
| Autor: | Koji Nakabayashi, Keisuke Tomono, Yoshihide Tsunobuchi, Wataru Kosaka, Shin-ichi Ohkoshi |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 11, Pp i79-i80 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809039336 |
| Popis: | The asymmetric unit of the title compound, KI4[MoIII(CN)7]·2H2O, consists of one [Mo(CN)7]4− anion, four K+ cations, and two water molecules. The [MoIII(CN)7]4− anion has a seven-coordinated capped-trigonal-prismatic coordination geometry. The site-occupancy factors of the disordered water molecules were set at 0.90, 0.60 and 0.50. The H-atom positions could not be determined for two of the water molecules. The H atoms of the water with a site-occupancy factor of 0.90 were refined using O—H and H...H distance restraints. |
| Databáze: | Directory of Open Access Journals |
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