| Popis: |
The present work aims at cost-effective approaches for biodiesel conversion from niger seed (NS) oil by employing the transesterification process, Box–Behnken design (BBD), and artificial intelligence (AI) tools. The performances of biodiesel yield are reliant on transesterification variables (methanol-to-oil molar ratio M:O, reaction time Rt, catalyst concentration CC, and reaction temperature RT). BBD matrices representing the transesterification parameters were utilized for experiment reductions, analyzing factor (individual and interaction) effects, deriving empirical equations, and evaluating prediction accuracy. M:O showed a dominant effect, followed by CC, Rt, and RT, respectively. All two-factor interaction effects are significant, excluding the two interactions (Rt with RT and M:O with RT). The model showed a good correlation or regression coefficient with a value equal to 0.9869. Furthermore, the model produced the best fit, corresponding to the experimental and predicted yield of biodiesel. Three AI algorithms were applied (the big-bang big-crunch algorithm (BB-BC), firefly algorithm (FA), and grey wolf optimization (GWO)) to search for the best transesterification conditions that could maximize biodiesel yield. GWO and FA produced better fitness (biodiesel yield) values compared to BB-BC. GWO and FA experimental conditions resulted in a maximum biodiesel yield equal to 95.3 ± 0.5%. The computation time incurred in optimizing the biodiesel yield was found to be equal to 0.8 s for BB-BC, 1.66 s for GWO, and 15.06 s for FA. GWO determined that the optimized condition is recommended for better solution accuracy with a slight compromise in computation time. The physicochemical properties of the biodiesel yield were tested according to ASTM D6751-15C; the results are in good agreement and the biodiesel yield would be appropriate to use in diesel engines. |
