Dissociation and Self-Preservation of Gas Hydrates in Permafrost

Autor: Evgeny Chuvilin, Boris Bukhanov, Dinara Davletshina, Sergey Grebenkin, Vladimir Istomin
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Geosciences, Vol 8, Iss 12, p 431 (2018)
Druh dokumentu: article
ISSN: 2076-3263
DOI: 10.3390/geosciences8120431
Popis: Gases releasing from shallow permafrost above 150 m may contain methane produced by the dissociation of pore metastable gas hydrates, which can exist in permafrost due to self-preservation. In this study, special experiments were conducted to study the self-preservation kinetics. For this, sandy samples from gas-bearing permafrost horizons in West Siberia were first saturated with methane hydrate and frozen and then exposed to gas pressure drop below the triple-phase equilibrium in the “gas⁻gas hydrate⁻ice„ system. The experimental results showed that methane hydrate could survive for a long time in frozen soils at temperatures of −5 to −7 °C at below-equilibrium pressures, thus evidencing the self-preservation effect. The self-preservation of gas hydrates in permafrost depends on its temperature, salinity, ice content, and gas pressure. Prolonged preservation of metastable relict hydrates is possible in ice-rich sandy permafrost at −4 to −5 °C or colder, with a salinity of
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