catena-Poly[[(1,10-phenanthroline-κ2N,N′)copper(I)]-μ-thiocyanato-κ2N:S-[(1,10-phenanthroline-κ2N,N′)copper(I)]-μ-cyanido-κ2N:C]
| Autor: | Xi-Jun Ke, Dong-Sheng Li, Wen-Wen Dong, Jun Zhao |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 12, Pp m1577-m1577 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808037744 |
| Popis: | In the title complex, [Cu2(CN)(NCS)(C12H8N2)2], which was synthesized under hydrothermal conditions, both CuI atoms have a slightly distorted tetrahedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thiocyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu–CN–Cu–SCN}n chains are formed along [{overline 1}01]. |
| Databáze: | Directory of Open Access Journals |
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