1,3-Bis(4-tert-butylbenzyl)-4,5-dihydroimidazolium chloride monohydrate
| Autor: | Bekir Çetinkaya, smail Özdemir, Sedat Yaşar, Don VanDerveer, Hakan Arslan |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 2, Pp o310-o311 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809000452 |
| Popis: | In the title compound, C25H35N2+·Cl−·H2O, the imidazolidine ring adopts a twisted conformation, with a pseudo-twofold axis passing through the N—C—N carbon and the opposite C—C bond. The N—C—N fragment of the imidazolidine ring shows some degree of both double- and single-bond character due to partial electron delocalization. One of the tert-butyl groups is disordered over two conformations with occupancies of 0.714 (8) and 0.286 (8). In the crystal, O—H...Cl and C—H...O hydrogen bonds help to establish the packing. |
| Databáze: | Directory of Open Access Journals |
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