RbZnFe(PO4)2: synthesis and crystal structure

Autor: Abdessalem Badri, Mongi Ben Amara
Jazyk: angličtina
Rok vydání: 2016
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 8, Pp 1074-1076 (2016)
Druh dokumentu: article
ISSN: 2056-9890
20569890
DOI: 10.1107/S205698901601046X
Popis: A new iron phosphate, rubidium zinc iron(III) phosphate, RbZnFe(PO4)2, has been synthesized as single crystals by the flux method. This compound is isostructural to the previously reported KCoAl(PO4)2 [Chen et al. (1997). Acta Cryst. C53,1754–1756]. Its structure consists of a three-dimensional framework built up from corner-sharing PO4 and (Zn,Fe)O4 tetrahedra. This mode of linkage forms channels parallel to the [100], [010] and [001] directions in which the Rb+ ions are located.
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