catena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2O:O′)]

Autor: Fu-Lin Zhou, Zhi-Hua Du, Seik Weng Ng
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 67, Iss 6, Pp m673-m673 (2011)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536811015947
Popis: The polymeric title compound, [Ce(C7H3N2O6)3(C2H6OS)2]n, exists as a linear chain along [111] as the three dinitrobenzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-antiprismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO molecules are disordered in a 0.926 (3):0.074 (3) ratio.
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