Poly[dimethylammonium [aquadi-μ2-oxalato-yttriate(III)] trihydrate]
| Autor: | Yao-Kang Lv, Li-Hua Gan, Liang Xu, Hao-Wen Zheng, Cao Liu |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 7, Pp m837-m838 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811019209 |
| Popis: | The title complex, {(C2H8N)[Y(C2O4)2(H2O)]·3H2O}n, was obtained accidentally under hydrothermal conditions. The YIII atom is chelated by four oxalate ligands and one water molecule resulting in a distorted tricapped trigonal–prismatic geometry. Each oxalate ligand bridges two YIII atoms, thus generating a three-dimensional network with cavities in which the ammonium cations and lattice water molecules reside. Various O—H...O and N—H...O hydrogen-bonding interactions stabilize the crystal structure. The title complex is isotypic with the Eu and Dy analogues. |
| Databáze: | Directory of Open Access Journals |
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