Luz: um raro produto de reação
| Autor: | Fernando Heering Bartoloni, Luiz Francisco Monteiro Leite Ciscato, Mônica Melchioretto de Medeiros Peixoto, Ana Paula Fileno dos Santos, Cerize da Silva Santos, Sandro de Oliveira, Felipe Alberto Augusto, Ana Paula Eskildsen Pagano, Wilhelm Josef Baader, Erick Leite Bastos |
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| Jazyk: | English<br />Spanish; Castilian<br />Portuguese |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Química Nova, Vol 34, Iss 3, Pp 544-554 (2011) |
| Druh dokumentu: | article |
| ISSN: | 1678-7064 0100-4042 |
| DOI: | 10.1590/S0100-40422011000300030 |
| Popis: | The production of visible light by chemical reactions constitutes interesting and fascinating phenomena and several reaction mechanisms are discussed to rationalize excited state formation. Most efficient chemiluminescence reactions are thought to involve one or more electron transfer steps and chemiexcitation is believed to occur by radical annihilation. A brief introduction to the general principles of light production and the main known chemiexcitation mechanisms will be given here. Subsequently, recent results on the mechanistic elucidation of efficient chemiluminescence systems, as the peroxyoxalate reaction, the induced decomposition of phenoxy-substituted 1,2-dioxetanes and the catalyzed decomposition of new a-peroxylactones will be discussed. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
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