Bis(1-ethyl-4,4′-bipyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickelate(II)
| Autor: | Jian-Lan Liu, Wei-hua Ning, Yao Chen |
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| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 69, Iss 8, Pp m428-m428 (2013) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536813015493 |
| Popis: | In the anion of the title compound, (C12H13N2)[Ni(C4N2S2)2], the NiII atom is coordinated by four S atoms from two 1,2-dicyanoethene-1,2-dithiolate (mnt) ligands in a suqare-planar geometry. Weak C—H...N and C—H...S hydrogen bonds between the 1-ethyl-4,4′-bipyridin-1-ium cations and mnt anions and weak π–π interactions between the pyridine rings of the cations [centroid–centroid distances = 3.808 (3) and 3.972 (3) Å] lead to a two-dimensional network parallel to (010). |
| Databáze: | Directory of Open Access Journals |
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