Tetrakis(μ-phenoxyacetato-κ2O:O′)bis[(1,10-phenanthroline-κ2N,N′)manganese(II)] methanol hemisolvate
| Autor: | Dong-Hui Wu, Jian Shi, Yu-Jun Shi, Guo-Qing Jiang |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 1, Pp m161-m161 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536807065269 |
| Popis: | The title complex, [Mn2(C8H7O3)4(C12H8N2)2]·0.5CH3OH, is a carboxylate-bridged dinuclear MnII complex with four phenoxyacetate ions and two 1,10-phenanthroline molecules as ligands. Each of the four phenoxyacetate anions bridges the pair of Mn atoms. The asymmetric unit is completed by a half-occupancy methanol solvent molecule. Face-to-face π–π stacking interactions between the aromatic rings of 1,10-phenanthroline molecules belonging to adjacent Mn2 complexes, with an interplanar separation of circa 3.4 Å, and weak C—H...O hydrogen bonds connect the dinuclear units into a three-dimensional supramolecular framework. |
| Databáze: | Directory of Open Access Journals |
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