Mono- and Dinuclear Aluminium Complexes Derived from Biguanide and Carbothiamide Ligands

Autor:	Maximilian Dehmel, Helmar Görls, Robert Kretschmer
Jazyk:	angličtina
Rok vydání:	2021
Předmět:	aluminium biguanides ligand design nitrogen ligands Inorganic chemistry QD146-197
Zdroj:	Inorganics, Vol 9, Iss 7, p 52 (2021)
Druh dokumentu:	article
ISSN:	2304-6740
DOI:	10.3390/inorganics9070052
Popis:	Dianionic N,N-chelating ligands play a crucial role in coordination chemistry, but reports on related complexes remain limited to certain types of ligands. In here, the reactions of two diprotic ligands, i.e., a biguanide and a carbothiamide, with trimethylaluminium, are reported, which give rise to mono- and dinuclear aluminium(III) complexes. In addition, single deprotonation of the diprotic biguanide using potassium bis(trimethylsilyl)amide gives rise to a one-dimensional coordination polymer. All complexes have been fully characterized, and their solid-state structures were determined by single crystal X-ray diffraction analysis.
Databáze:	Directory of Open Access Journals
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