Ultrahigh Adsorption Capacity Zirconium-Magnesium Composite Oxide Nanoclusters Remove Malachite Green from Aqueous Media

Autor: Yulong Sun, Haoxin Zheng, Yanfeng Pu, Hao Yang, Jianhong Wang, Shuaishuai Zhou, Qian Li, Congzhen Qiao
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Adsorption Science & Technology, Vol 2022 (2022)
Druh dokumentu: article
ISSN: 2048-4038
DOI: 10.1155/2022/1946955
Popis: The environmental pollution caused by organic dyes has damaged serious harm to human life. Hence, a series of Zr-Mg composite oxide nanoclusters with different metal ratios were synthesized by solvothermal method for adsorption of malachite green in aqueous solution. The optimal adsorbent with Zr/Mg metal molar ratio of 1 : 2 presented good adsorption performance, which adsorption capacity reached 12647.60 mg/g, and removal rate of malachite green reached more than 99%. These adsorbents were characterized by X-ray diffraction, Fourier-transform infrared spectra, nitrogen adsorption-desorption, scanning electron microscope, transmission electron microscope, and other methods. Influence of initial concentration of malachite green solution, pH, adsorption temperature, and contact time on absorption efficiency was investigated through batch experiments. Pseudo-second-order kinetic model can well describe the adsorption kinetic data. The three-parameter Sips isotherm model was more suitable for predicting the experimental results than Langmuir and Freundlich, and the adsorption process was endothermic.
Databáze: Directory of Open Access Journals
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