| Autor: |
NEVENKA BOSKOVIC–VRAGOLOVIC, RADMILA GARIC–GRULOVIC, ZELJKO GRBAVCIC |
| Jazyk: |
angličtina |
| Rok vydání: |
2007 |
| Předmět: |
|
| Zdroj: |
Journal of the Serbian Chemical Society, Vol 72, Iss 11, Pp 1103-1113 (2007) |
| Druh dokumentu: |
article |
| ISSN: |
0352-5139 |
| Popis: |
The electrochemical oxidation of methanol in NaOH solution was examined on a thin film Pt2Ru3/C electrode. The XRD pattern revealed that the Pt2Ru3 alloy consisted of a solid solution of Ru in Pt and a small amount of Ru or a solid solution of Pt in Ru. It was shown that in alkaline solution, the difference in activity between Pt/C and Pt2Ru3/C is significantly smaller than in acid solution. It is proposed that the reaction follows a quasi bifunctional mechanism. The kinetic parameters indicated that the chemical reaction between adsorbed COad and OHad species could be the rate limiting step. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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