Crystal structure of 2-benzylamino-4-(4-bromophenyl)-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile

Autor:	R. A. Nagalakshmi, J. Suresh, S. Maharani, R. Ranjith Kumar, P. L. Nilantha Lakshman
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	crystal structure cyclopentane ring envelope conformation N—H...N hydrogen bonding π–π interactions Crystallography QD901-999
Zdroj:	Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 3, Pp 296-298 (2015)
Druh dokumentu:	article
ISSN:	2056-9890 20569890
DOI:	10.1107/S2056989015002820
Popis:	In the title compound C22H18BrN3, the cyclopentane ring adopts an envelope conformation with the central methylene C atom as the flap. The dihedral angles between the central pyridine ring and the pendant benzyl and and bromobenzene rings are 82.65 (1) and 47.23 (1)°, respectively. In the crystal, inversion dimers linked by pairs of N—H...Nn (n = nitrile) hydrogen bonds generate R22(12) loops. These dimers are linked by weak π–π interactions [centroid–centroid distance = 3.7713 (14) Å] into a layered structure.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/7b3ca6c5126f4935815ef562a38859fa Zobrazit plný text záznamu View record in DOAJ