| Autor: |
Yuying Yang, Yabin Zhang, Yuxin Song, Tingbin Ma, Luqing Zhang, Shuxiang Zhang |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
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| Zdroj: |
Energies, Vol 17, Iss 14, p 3398 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
1996-1073 |
| DOI: |
10.3390/en17143398 |
| Popis: |
Considerable research has been conducted on single-ion conductive polymeric electrolytes with high lithium ion transference numbers. However, low ionic conductivity is a long-standing challenge for lithium metal batteries, hindering the development of extending their cycle life. In this study, we synthesized a novel fluorine-containing single-ion polymeric electrolyte, LiP(VDF-co-MAF)BB (Polyvinylidene fluoride trifluoromethyl acrylate lithium borate polymer; subsequently referred to as PPMBB), exhibiting a room temperature conductivity of 1.03 × 10−3 S/cm. This electrolyte demonstrates a high lithium ion transference number of 0.7901 and an extended electrochemical stability window of 5.5 V. Under a 2 C discharge rate, it manifests a remarkable discharge specific capacity of 146.8 mAh/g. Moreover, even after 364 cycles, the capacity retention remains at 76%. The single-ion polymeric gel electrolyte designed in this work provides a promising strategy for the prolonged cycling performance of lithium metal batteries. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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