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Developing and optimizing new reactive systems with carbon-neutral fuels like biofuels, e-fuel, hydrogen, or ammonia is crucial for sustainable energy. This requires advanced technologies capable of fuel flexibility, high efficiency, and minimal pollutant emissions. However, these energy carriers still produce pollutants, especially NOx. To address this, engineers aim to lower combustion process temperatures by adopting different strategies such as burned gas recirculation, staging or increasing the air-to-fuel ratio. Yet, lean flames, though effective at emission reduction, are prone to instability and extinction, posing safety and mechanical risks. Emerging technologies like MILD Combustion, based on burned gas recirculation and reactant dilutions offer interesting solutions. The review article begins by synthesizing experimental studies and numerical simulations of MILD turbulent combustion. It then explores fundamental phenomena specific to diluted combustion (where MILD regimes are included as sub-sets), including autoignition and flame propagation. Using high-fidelity simulations and advanced experiments, it examines flow and mixing roles in reactive zones stabilization. Moving forward, the review paper addresses the inclusion of detailed chemical properties in modeling turbulent combustion systems. Scientific challenges revolve around modeling the intricate interactions between combustion chemistry and flow turbulence while maintaining computational efficiency compatible with industrial constraints. To address this, various simplified chemistry methods – such as reduced, tabulated, or optimized chemistry – have been developed. Additionally, turbulence/chemistry coupling modeling remains unresolved in simulations, with three main routes – geometrical, statistical, or reactor-based approaches – available for turbulent combustion modeling. The state-of-the-art in simplified chemistry and turbulent combustion modeling for low-temperature regimes is then focused on capturing MILD regimes, where there is a crucial impact of dilution by burnt gases, heat transfer, and turbulence mixing on the chemical flame structure. Recent advancements enabled by machine learning and deep learning algorithms are also highlighted. Lastly, the article underscores the critical need for data to validate models, emphasizing the importance of scale-bridging experiments. |