| Autor: |
Changyou Liu, Ketian Hou, Bei Zhang |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
Results in Physics, Vol 57, Iss , Pp 107340- (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2211-3797 |
| DOI: |
10.1016/j.rinp.2024.107340 |
| Popis: |
Two new nitrates Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl2 have been synthesized by hydrothermal method, and they are crystallized in orthorhombic space group Pnma (no. 62) and tetragonal space group P4/mnc (no. 128), respectively. ZnCl4 and RbO3Cl6 polyhedron, NaO4Cl2 and RbO8Cl2 polyhedron are connected by sharing O or Cl atoms to construct three-dimensional (3D) frameworks with trigonal plane NO3 units as pseudo-layers, in which different types of channels are presented. In addition, Rb5Na(NO3)4Cl2 exhibits a perovskite-related framework, and Rb3ZnNO3Cl4 crystals is grown with dimensions up to 5×4.5×1 mm3. Notably, these two compounds have short UV cut-off edge (below 222 nm and 238 nm, respectively). Theoretical calculations indicate that the birefringence enhancement is mainly derived from π-conjugated NO3 units. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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