Porous polymer bilayer with near-ideal solar reflectance and longwave infrared emittance

Autor: Tsang Yung Chak Anson, Varghese Nithin Jo, Degeorges Mathis, Mandal Jyotirmoy
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Nanophotonics, Vol 13, Iss 5, Pp 669-677 (2024)
Druh dokumentu: article
ISSN: 2192-8614
DOI: 10.1515/nanoph-2023-0707
Popis: This study explores the optical design of a daytime radiative cooler with near-ideal solar reflectance and longwave infrared (LWIR) emittance through materials selection and nanostructuring. Focusing on polymers as a materials platform, we introduce a bilayer architecture, comprising a porous poly(vinylidene fluoride-co-hexafluoropropene) (P(VdF-HFP)) topcoat that serves as a low-index LWIR emissive effective medium, over a nanofibrous, solar scattering polytetrafluoroethene underlayer. This novel configuration yields a superwhite coating with a near-ideal solar reflectance of >0.99, and a blackbody-like near-normal and hemispherical LWIR emittances of ∼0.98 and ∼0.96 respectively. Under humid and partially cloudy sky conditions unfavorable for radiative heat loss, these values enable the bilayer radiative cooler to achieve a sub-ambient of 2.3 °C. Given that the porous polymer bilayer uses scalable fabrication processes and commercially available materials, it holds significant promise for device-scale, as well as building thermoregulation applications.
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