SEPARATION AND PRECONCENTRATION OF COPPER (II) ION BY FATTY HYDROXAMIC ACIDS IMMOBILIZED ONTO AMBERLITE XAD – 4 RESIN

Autor: Dedy Suhendra, W. M. Z. Wan Yunus, Md. Jelas Haron, Mahiran Basri, Sidik Silong
Jazyk: angličtina
Rok vydání: 2010
Předmět:
Zdroj: Indonesian Journal of Chemistry, Vol 6, Iss 2, Pp 165-169 (2010)
Druh dokumentu: article
ISSN: 1411-9420
2460-1578
DOI: 10.22146/ijc.21754
Popis: A method of copper (II) ion preconcentration and separation from other ions by using a column containing fatty hydroxamic acids - loaded Amberlite XAD 4 resin (FHA-Amb) is described. Several factors, which affect the separation and preconcentration efficiency such as pH, sample volume, and concentration of eluent and flow rate, have been investigated. A quantitative recovery of copper (II) ion from FHA-Amb resin column was obtained using 10% HNO3 solutions as eluent with a preconcentration factor of 60. A method for separation of Cu(II) from Zn(II) and Cd(II) is proposed. A rapid sample throughput, a clean separation, a high preconcentration factor and simplicity are the main advantages in these analytical procedures. Keywords: extraction, preconcentration, fatty hydroxamic acid, copper (ii) ion, amberlite XAD-4
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