Cyclopentadienyl Ruthenium(II) Complex-Mediated Oxidation of Benzylic and Allylic Alcohols to Corresponding Aldehydes

Autor:	Ching-Yuh Chern, Ching-Chun Tseng, Rong-Hong Hsiao, Fung Fuh Wong, Yueh-Hsiung Kuo
Jazyk:	angličtina
Rok vydání:	2019
Předmět:	Organic chemistry QD241-441 Inorganic chemistry QD146-197
Zdroj:	Heteroatom Chemistry, Vol 2019 (2019)
Druh dokumentu:	article
ISSN:	1042-7163 1098-1071
DOI:	10.1155/2019/5053702
Popis:	This work reports an efficient method for the oxidation reaction of aliphatic, aromatic allylic, and benzylic alcohols into aldehydes catalyzed by the cyclopentadienyl ruthenium(II) complex (RuCpCl(PPh3)2) with bubbled O2. Through further optimizing controlled studies, the tendency order of oxidation reactivity was determined as follows: benzylic alcohols > aromatic allylic alcohols >> aliphatic alcohols. In addition, this method has several advantages, including a small amount of catalyst (0.5 mol%) and selective application of high discrimination activity of aliphatic, aromatic allylic, and benzylic alcohols.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/ece78e5f4e484871a8f354d2c35a2a36 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.