(Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate

Autor: Yong-Feng Zhao, Jin-Ping Xiong, Yu Zuo
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 65, Iss 7, Pp o1477-o1477 (2009)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536809020224
Popis: The title compound, C18H12N2O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intramolecular N—H...O interaction results in the formation of a planar six-membered ring, which is oriented at dihedral angles of 13.50 (4) and 4.49 (4)° with respect to the benzene ring and naphthalene ring system, respectively. In the crystal structure, intermolecular C—H...O and C—H...N interactions link the molecules into a two-dimensional network. π–π contacts between the naphthalene systems [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure.
Databáze: Directory of Open Access Journals