Calcium ionophore I as very effective extraction agent for trivalent europium and americium

Autor: Makrlík Emanuel, Vaňura Petr
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Journal of the Serbian Chemical Society, Vol 84, Iss 2, Pp 199-209 (2019)
Druh dokumentu: article
ISSN: 0352-5139
1820-7421
DOI: 10.2298/JSC180219111M
Popis: The solvent extraction of microamounts of Eu3+ and Am3+ from water into nitrobenzene by means of a mixture of hydrogen dicarbollylcobaltate (H+B-) and calcium ionophore I (marked as the ligand L) was investigated. The equilibrium data have been explained assuming that the species HL+, HL2 +,ML2 3+ and ML3 3+ (M3+: Eu3+ or Am3+) are extracted into the organic phase. The extraction and stability constants of the cationic complex species in nitrobenzene saturated with water have been determined and discussed. It was proven experimentally that the ligand L could be considered as a very strong receptor for Eu3+ and Am3+.
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