| Autor: |
K. Gurushantha, K. S. Anantharaju, Nagaraju Kottam, K. Keshavamurthy, C. R. Ravikumar, B. S. Surendra, A. Murugan, H. C. Ananda Murthy |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
|
| Zdroj: |
Adsorption Science & Technology, Vol 2022 (2022) |
| Druh dokumentu: |
article |
| ISSN: |
2048-4038 |
| DOI: |
10.1155/2022/5664344 |
| Popis: |
Solution combustion was employed to create a series of ZrO2:Dy3+ (1-11 mol percent) nanoparticles (NPs) using oxalyl dihydrazide (ODH) as the fuel. ZrO2:Dy3+ NPs were subjected to calcination at about 700°C. ZrO2:Dy3+ NPs comprised of 1 to 11 mol% of Dy3+ were characterized by employing the X-ray diffraction (XRD), transmission electron microscopic (TEM), UV-visible, and X-ray photoelectron spectroscopic (XPS) techniques. The crystallite diameters of 1 to 11 mol% ZrO2:Dy3+ NPs were observed to range from 8.1 nm to 16.3 nm, exhibiting spherical shape. According to BET tests, the pore volume of ZrO2:Dy3+ NPs was determined to be 100.129 cm3/g. The mean pore diameter of ZrO2:Dy3+ NPs was determined to be 4.803 nm from the Barrett-Joyner-Halenda (BJH) plot. The photoluminescence and photocatalytic dye degradation properties of ZrO2:Dy3+ NPs were investigated. The acid red 88 (AR88) dye was applied to appraise the photocatalytic activities of the NPs under UV irradiation. ZrO2:Dy3+ NPs with 3 mol% Dy3+ exhibited improvised photocatalytic activity due to the operative departure of charge carriers. The electrochemical examination of ZrO2:Dy3+ NP modified carbon paste electrode in 0.1 N HCl demonstrated considerable redox potential output, as evidenced by cyclic voltammetric and amperometric measurements. The electrochemical sensor studies on ZrO2:Dy3+ NPs exhibited potentiality towards sensing of highly toxic metals like mercury and lead. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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