(2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I)
| Autor: | William W. Brennessel, John E. Ellis |
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| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 5, Pp m180-m180 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 |
| DOI: | 10.1107/S1600536814006758 |
| Popis: | The title salt, [K(C18H36N2O6)][Co(CO)4], is an example of a classical carbonylmetalate. The asymmetric unit contains one cation and one tetrahedral anion, both in general positions. Based on comparison of the four carbonyl C—O bond lengths and C—Co—C angles, the anion is unperturbed by the cation, which is normal for an alkali metal fully encased by a cryptand cage. |
| Databáze: | Directory of Open Access Journals |
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