High-performance asymmetric supercapacitor based on vanadium dioxide and carbonized iron-polyaniline electrodes
Autor: | N. M. Ndiaye, M. J. Madito, B. D. Ngom, T. M. Masikhwa, A. A. Mirghni, N. Manyala |
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Jazyk: | angličtina |
Rok vydání: | 2019 |
Předmět: | |
Zdroj: | AIP Advances, Vol 9, Iss 5, Pp 055309-055309-9 (2019) |
Druh dokumentu: | article |
ISSN: | 2158-3226 |
DOI: | 10.1063/1.5091799 |
Popis: | Vanadium dioxide (VO2) monoclinic nanosheets were synthesized by a solvothermal method and carbonized iron-polyaniline (C-FP) nanograins were prepared by pyrolysis of iron-polyaniline (PANI) mixture under nitrogen ambient. An asymmetric device (VO2//C-FP) was evaluated with VO2 and C-FP as positive and negative material electrodes in aqueous 6 M KOH electrolyte respectively. The asymmetric supercapacitor (VO2//C-FP) exhibited a 47 mA h g-1 specific capacity and a specific energy of 30 W h kg−1 with an associated specific power of 713 W kg−1 at a gravimetric current of 1 A g−1 in a potential window of 1.6 V. It also displayed an 89% energy efficiency after 10000 galvanostatic charge-discharge cycles with a large improvement after ageing test at a gravimetric current of 10 A g-1. |
Databáze: | Directory of Open Access Journals |
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