Synthesis and crystal structure of bis(2-aminobenzimidazolium) catena-[metavanadate(V)]

Autor: Kholida Jabborova, Jamshid Ashurov, Akmaljon Tojiboev, Shahlo Daminova
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 7, Pp 751-754 (2024)
Druh dokumentu: article
ISSN: 2056-9890
20569890
DOI: 10.1107/S2056989024005528
Popis: The structure of polymeric catena-poly[2-aminobenzimidazolium [[dioxidovanadium(V)]-μ-oxido]], {(C7H8N3)2[V2O6]}n, has monoclinic symmetry. The title compound is of interest with respect to anticancer activity. In the crystal structure, infinite linear zigzag vanadate (V2O6)2− chains, constructed from corner-sharing VO4 tetrahedra and that run parallel to the a axis, are present. Two different protonated 2-aminobenzimidazole molecules are located between the (V2O6)2– chains and form classical N—H...O hydrogen bonds with the vanadate oxygen atoms, which contribute to the cohesion of the structure.
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