Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)diformato-κ2O,O′;κO-nickel(II) monohydrate
| Autor: | Ping Xia, Jian-Li Lin, Sheng-Liang Ni |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 9, Pp m1181-m1181 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811030558 |
| Popis: | The asymmetric unit of the title compound, [Ni(HCO2)2(C14H12N2)(H2O)]·H2O, contains a mononuclear complex molecule hydrogen bonded to a lattice water molecule. The NiII atom exhibits a distorted octahedral coordination geometry formed by the N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, two O atoms of a chelating formate anion, one aqua O atom and one O atom of a coordinating formate anion. The molecules are assembled into chains extending along [100] through by O—H...O hydrogen bonds. The supramolecular chains are further linked into layers parallel to (011) by weak π–π packing interactions [centroid–centroid separation = 3.768 (2) Å]. The resulting layers are stacked to meet the requirement of close-packing patterns. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|