Valorization of tree leaves waste using microwave‐assisted hydrothermal carbonization process

Autor: Kang Kang, Tianle Zhang, Guotao Sun, Mingqiang Zhu, Kankan Li, Dongbing Li
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: GCB Bioenergy, Vol 13, Iss 10, Pp 1690-1703 (2021)
Druh dokumentu: article
ISSN: 1757-1707
1757-1693
DOI: 10.1111/gcbb.12882
Popis: Abstract Fallen leaves of landscape trees, as an emerging biomass waste, were valorized using conventional hydrothermal carbonization (HC) and microwave‐assisted hydrothermal carbonization (MHC) pretreatments, and were comparatively characterized for physicochemical properties and thermal degradation kinetics. The results show that MHC is superior to conventional HC operation, because at 200℃, the MHC process not only gives a higher hydrochar yield (45.09 vs. 39.47 wt%) with significantly reduced energy consumption (0.63 vs. 2.74 MJ g−1), but also is more effective in removing K and Si. For isoconversional kinetic analysis, the FWO method provides better results than the KAS method as the latter failed to fit the tree leaves sample (R2 400℃) showed that the hydrochar obtained from the MHC process has a lower average activation energy of ~190 MJ kg−1 than the conventional HC process (~260 MJ kg−1). This study reveals the potential for valorization of the landscape tree wastes via the MHC process.
Databáze: Directory of Open Access Journals
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