Brette Pearl Spar Mable (BPSM): a potential recoverable catalyst as a renewable source of biodiesel from Thevetia peruviana seed oil for the benefit of sustainable development in West Africa

Autor: T. F. Adepoju, B. E. Olatunbosun, O. M. Olatunji, M. A. Ibeh
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Energy, Sustainability and Society, Vol 8, Iss 1, Pp 1-17 (2018)
Druh dokumentu: article
ISSN: 2192-0567
DOI: 10.1186/s13705-018-0164-1
Popis: Abstract Background The energy requirements are globally on a rapid escalation, as technology advances, which is also true for a developing country like Nigeria, which is dependent on fossil fuels and its derivatives. Apart from its adverse effect on its economy, it has also negative impacts on the health and the environment, in general. However, investments in renewable energy are faced by the competitive oil prices, the very high investment cost for renewable energy, and high local electricity prices. This paper appraises the attractiveness of investing in renewable energy sources over the continued use of non-edible oil for electricity generation. Methods This paper explores the application of biomass seed oil to produce a renewable fuel (biodiesel) using heterogeneous base catalyst. Meanwhile, two-step processes were employed to produce the biofuel. In the first step (esterification), the acid value of the oil was reduced to the recommended limit (FFA ≤ 1.5) using H2SO4, while in the second step (transesterification), the catalyst calcination of grounded Brette Pearl Spar Mable (BPSM) pre-soaked in methanol was used as a biobase for biodiesel production. For the optimization, minitab response surface (MRS) and artificial neural network (ANN) were employed to model and optimize the process variables responsible for the optimum production of the oil and the biodiesel. Results The result presented showed that T. peruviana seed was found to be rich in oil with an average yield of 44.00% (w/w), and the oil was highly unsaturated with a high FFA. The maximum experimental biodiesel yield obtained was 86.00% at a catalyst amount of 4 g, a reaction time of 70 min, and a methanol/oil ratio of 0.1(v/v). This result was validated in triplicate under the same conditions, which yielded 85.70% (v/v) for MRS and 85.98% (v/v) for ANN. Furthermore, the optimization results also indicated that the p values (p
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