Chemoselective C-benzoylation of phenols by using AlCl3 under solvent-free conditions

Autor:	S. V. Gaikwad, B. R. Nawghare, P. D. Lokhande
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	Chemoselective C-acylation F-C reaction Fries rearrangement Chemistry QD1-999
Zdroj:	Bulletin of the Chemical Society of Ethiopia, Vol 29, Iss 2, Pp 319-325 (2015)
Druh dokumentu:	article
ISSN:	1011-3924 1726-801X
DOI:	10.4314/bcse.v29i2.14
Popis:	Substituted phenols were chemo-selectively reacted with benzoylchloride in presence of aluminum chloride under solvent-free condition to afford the corresponding 2'-hydroxy aryl benzophenones in excellent yields (72-96%). Naphthol benzoylation resulted in lower yields as compared to phenols. Both reactions completed in 5-10 min with quantitative yields providing excellent control over regioselectivity of products.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/d754f6ecb72d47fb8fa49d460154ef88 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF