Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate
| Autor: | Jian-Zhang Li, Jun Wang, Bin Xie, Li-Ke Zou, Shen-Xin Li |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 5, Pp m477-m477 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809011702 |
| Popis: | In the title compound, [Ni(C6H16N2)2](NO3)2·H2O, the bis(2,3-dimethylbutane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-related 2,3-diamino-2,3-dimethylbutane (tmen) ligands. The amine groups are N—H...O hydrogen bonded to the nitrate anions, which are, in turn, linked by interstitial water molecules lying on a twofold axis. The infinite zigzag chains thus formed along [001] are further connected to each other by N—H...O hydrogen bonds towards the water molecules, forming layers of two-dimensional hydrogen-bonded arrays. |
| Databáze: | Directory of Open Access Journals |
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