Bis[(2-pyridyl)(2-pyridylamino)methanolato]manganese(III) nitrate
| Autor: | Shuai Ding, Congjun Xia, Yufei Ji, Zhiliang Liu, Yong Ding |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 5, Pp m622-m623 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811014371 |
| Popis: | The MnIII atom in the title complex, [Mn(C11H10N3O)2]NO3, is coordinated by the two tridentate (2-pyridyl)(2-pyridylamino)methanolate ligands, forming a six-coordinate environment. The four pyridyl N atoms constitute the equatorial plane on which the manganese(III) ion lies; the coordination plane suffers a slight distortion as indicated by the average plane deviation of 0.058 Å. The methanolate O atoms occupy the axial positions. The coordination geometry is thus octahedral. In the title compound, the cations are linked by nitrate anions via N—H...O hydrogen bonds to form one-dimensional chains. Moreover, the one-dimensional structure is stabilized by intermolecular edge-to-face aromatic π–π interactions with a center-of-inversion at a distance of ca 4.634 Å. |
| Databáze: | Directory of Open Access Journals |
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