Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin
| Autor: | Ze-Yu Liu, Mian HR Mahmood, Jian-Zhong Wu, Shu-Bao Yang, Hai-Yang Liu |
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| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: | |
| Zdroj: | Molecules, Vol 22, Iss 11, p 1941 (2017) |
| Druh dokumentu: | article |
| ISSN: | 1420-3049 |
| DOI: | 10.3390/molecules22111941 |
| Popis: | A one-pot synthesis of bulky bis-pocket A3B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxidant and the cyanating agent. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
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