Statistical optimization of guest uptake in crystalline sponges: grading structural outcomes

Autor:	Robert C. Carroll, Simon J. Coles
Jazyk:	angličtina
Rok vydání:	2024
Předmět:	crystalline sponges statistical design of experiments metal–organic frameworks single-crystal x-ray diffraction scxrd Crystallography QD901-999
Zdroj:	IUCrJ, Vol 11, Iss 4, Pp 578-586 (2024)
Druh dokumentu:	article
ISSN:	2052-2525 20522525
DOI:	10.1107/S2052252524004871
Popis:	Investigation of the analyte soaking conditions on the crystalline sponge {[(ZnI2)3(tpt)2·x(solvent)]n} method using a statistical design of experiments model has provided fundamental insights into the influence of experimental variables. This approach focuses on a single analyte tested via 60 experiments (20 unique conditions) to identify the main effects for success and overall guest structure quality. This is employed as a basis for the development of a novel molecular structure grading system that enables the quantification of guest exchange quality.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/737ad0270fac4ab798e35d6c6cbb0ae8 Zobrazit plný text záznamu View record in DOAJ