2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide
| Autor: | Viviane Conceição Duarte de Bittencourt, Juliano Rosa de Menezes Vicenti, Jecika Maciel Velasques, Priscilla Jussiane Zambiazi, Vanessa Carratu Gervini |
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| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 1, Pp o64-o65 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 |
| DOI: | 10.1107/S1600536813033369 |
| Popis: | The title molecule, C9H7ClN4OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intramolecular N—H...O and N—H...N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, molecules are assembled into inversion dimers through pairs of co-operative N—H...Cl interactions. These dimers are connected along the b axis by N—H...O and N—H...S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π–π stacking interactions [centroid–centroid distance = 3.849 (2) Å]. |
| Databáze: | Directory of Open Access Journals |
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